(E)-3-(2-Chloro-3,3,3-trifluoroprop-1-enyl)-N-(3-methoxyphenyl)-2,2-dimethylcyclopropanecarboxamide

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(E)-3-Chloro-N′-hy­droxy­benzene-1-carboximidamide

The title compound, C7H7ClN2O, crystallizes with two independent mol-ecules in the asymmetric unit. The compound adopts an E configuration across the C=N double bond, as the -OH group and the benzene ring are on opposite sides of the double bond while the H atom of the hy-droxy group is directed away from the -NH2 group. In the crystal, mol-ecules are linked to one another through O-H⋯N and N-H...

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(E)-3-Chloro-N-[(2-eth­oxy­naphthalen-1-yl)methyl­idene]aniline

In the title compound, C(19)H(16)ClNO, the dihedral angle between the naphthalene ring system and the chloro-benzene ring is 61.90 (10)° and the C-N-C-C torsion angle is 174.6 (2)°. The mol-ecular structure is stabilized by an intra-molecular C-H⋯N hydrogen bond. The crystal structure features π-π stacking inter-actions [centroid-centroid distances = 3.7325 (17) and 3.8150 (17) Å].

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The title Schiff base compound, C(16)H(14)ClN, adopts E configurations with respect to both the C=C and C=N bonds. The dihedral angle between the two aromatic rings is 53.27 (4)°, while the plane through the C=C-C=N system is inclined at 9.06 (8)° to the benzene ring and 44.92 (5)° to the chloro-benzene ring. In the crystal structure, weak C-H⋯Cl and C-H⋯N hydrogen bonds stack the mol-ecules do...

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(E)-3-Chloro-N′-(2-fluoro­benzyl­idene)thio­phene-2-carbohydrazide

The title compound, C12H8ClFN2OS, is a hydrazide derivative adopting an E conformation with an azomethine N=C double bond length of 1.272 (2) Å. The mol-ecular skeleton is approximately planar; the terminal five- and six-membered rings form a dihedral angle of 5.47 (9)°. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds into zigzag chains propagating in [100].

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(E)-3-(2-Chloro-3,3,3-trifluoro­prop-1-en­yl)-N-(3-methoxy­phen­yl)-2,2-dimethyl­cyclo­propane­carboxamide

The title compound, C(16)H(17)ClF(3)NO(2), was synthesized from 3-[(E)-2-chloro-3,3,3-trifluoro-prop-1-en-yl]-2,2-dimethyl-cyclo-propane-carboxylic acid and 3-methoxy-benzenamine. The propenyl and carboxamide substituents lie on the same side of the cyclo-propane ring plane, with the two methyl substituents on either side of the plane. The benzene ring makes a dihedral angle of 76.4 (3)° with t...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2007

ISSN: 1600-5368

DOI: 10.1107/s1600536807063167